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Biaxial nematic phase in the Maier-Saupe model for a mixture of discs and cylinders

机译:maier-saupe模型中的双轴向列相,用于混合盘   和气缸

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摘要

We analyze the global phase diagram of a Maier-Saupe lattice model with theinclusion of disorder degrees of freedom to mimic a mixture of oblate andprolate molecules (discs and cylinders). In the neighborhood of a Landaumulticritical point, solutions of the statistical problem can be written as aLandau-de Gennes expansion for the free energy. If the disorder degrees offreedom are quenched, we confirm the existence of a biaxial nematic strucure.If orientational and disorder degrees of freedom are allowed to thermalize,this biaxial solution becomes thermodynamically unstable. Also, we use atwo-temperature formalism to mimic the presence of two distinct relaxationtimes, and show that a slight departure from complete thermalization is enoughto stabilize a biaxial nematic phase.
机译:我们分析了Maier-Saupe晶格模型的整体相图,其中包括模仿扁圆形和扁形分子(圆盘和圆柱体)的自由度的无序度。在Landau多临界点附近,可以将统计问题的解决方案写为自由能的Landau-de Gennes展开。如果无序自由度被淬灭,我们确认存在双轴向列结构。如果允许取向和无序自由度热化,则该双轴解变得热力学不稳定。同样,我们使用二温形式主义来模拟两个不同弛豫时间的存在,并表明完全完全热化的轻微偏离足以稳定双轴向列相。

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